Electron dot formulas clarify the mechanism of forming a coordinate bond in the neutralization of a Lewis acid. Neutralization of a proton by an ammonia molecule is A
The acid — base pair Al3+ and H2O undergoes Lewis neutralization by forming six coordinate bonds.
Many displacement reactions illustrate the relative strength of the Lewis acid or base. For example, the cyanide ion is a stronger base than the fluoride ion by virtue of its ability to displace the fluoride ion from the hexafluoroferrate (III) ion: FeF63- + 6CN- ------→ Fe(CN)63- + 6F-
There are many reactions that fit the Lewis acid-base concept. In contrast to proton loss or gain in the Bronsted-Lowry concept, the Lewis concept emphasizes the electron pair ------a Lewis acid lacks an electron pair in an empty orbital, or has an orbital that can be vacated and a Lewis base has a nonbonding electron pair and can supply this pair to another substance lacking an electron pair.
It is evident that the Lewis concept applies, not only to the chemical behavior correlated by the Bronsted-Lowry concept, but also to many chemical reactions that do not involve proton transfer, and for this reason it is most useful. Its generality precludes the establishment of a scale of acid and base strengths for all Lewis acids and bases, but comparisons can be made between selected substances.
The terms nucleophilic, and electrophilic are sometimes applied to bases and acids. Lewis acids that accept an electron pair are electrophilic, and the strength of Lewis bases is measured by their tendencies to supply electrons. For example,H2O is a stronger base than Cl- because H2O displaces Cl~ in supplying an electron pair for the proton:
HCl+H2O------→H3O+ + Cl-
Consequently , H2O is a stronger nucleophilic agent than Cl-.
哎,不知道这次有没有人来答,我已经N次提问了,呜....
救命啊。。。。。帮帮我!= =||、
化学专业英语翻译
Chemistry 化学专业中专业不用翻译,一般在英语对话中,对方会问你what's your major?(你的专业是什么?)你可以答my major is Chemistry. 或简略的答为Chemistry
化学专业英语翻译(中翻英)
reducing crude cyclohexanone and cyclohexanol mixture of light components in the methods and aids. In the light tower that is the feed concentration of KA oil add 5 to 20% of the additive potassium hydroxide solution,
化学专业英语翻译
Separately using ethanol ether mixture and petroleum ether processing pumpkin powder. Then in 90 ℃, solid-liquid ratio under the condition of chains, the use of traditional hot water leaching extraction four hours, filtering, with methanol precipitation of polysaccharides, through the filtr...
化学专业英语翻译短语
1.Solution surface tension can be used for the determination of low-value production of teaching aids and their performance measured 2.The surface tension of the existing meter is expensive, when used in teaching as a result of the number of students, and can not ensure that a st...
化学专业英语翻译^
楼主请看专业版:电子结构式清楚地说明了路易斯酸中和过程中配位键的形成机制。Neutralization of a proton by an ammonia molecule is A (用氨分子中和质子【注:即氢离子】是A。。。) 【该句原文不完整】(路易斯)酸碱对Al3+ 和 H2O 通过形成六个配位键发生中和反应。【注:该句前应有上文...
化学专业英文翻译
on the other hand, the membrane formation rate and PH value. This experiment mainly with open point - time curve method, Tafel curve method and salt spray test to study corrosion passivation solution PH value and passivation membrane resistance and determine the optimal PH value....
化学专业英语翻译
任何包含一个金属原子及其连接配体的天然化合物被称做配位化合物。
化学专业英语翻译
在典型的nanorods本研究以问卷调查法合成了紫外光海里的直径和300 - 500海里的长度。Meanwhile novel 与此同时,小说 structural meso-scale dumbbells uniformly grown in aqueous solution were firstly discovered with the length of 2.1 lm, diameter of 700, 800 and 450 nm in a larger end face...
化学专业英语 翻译
pinane ['painein]蒎烷,松节烷
化学专业英语翻译
Based on the microwave method with using sucroses as raw materials and concentrated hydrochloric acid as catalyst and acidifier,a product of levulinic acid and formic acid by-products are generated by the intermediate product 5 - hydroxymethyl-furfural and decarboxylation. The experimental ...